Office 2007 Training Videos - Start with Intro to Office 2007. (Use Mozilla FireFox if you can't view the videos in Internet Explorer.)
Office 2007 - Getting Started - Demos, help and training from Microsoft
Office 2007 Tutorials (Word, Excel, PowerPoint) - Start with the Office 2007 Overview.
In Pictures - Directions and tutorials for Word, Excel and PowerPoint.
Microsoft Office Clip Art - Free clip art and media collections.